Blake LivelyJoining the many stars scoping out the latest looks, Blake Lively ventured out for a taste of New York City’s Mercedes Benz Fashion Week Fall 2012 on Wednesday night (February 15).

The Serena van der Woodsen hottie looked darling in a white and black ensemble as she took to Provocateur for the Noon By Noor presentation.

On the career front, Miss Lively can next be seen in a new episode of her hit drama “Gossip Girl” – as ‘Cross Rhodes’ is set to air on Monday night (February 20) at 8/7c on The CW.

With a preview found below, a synopsis of the episode via the show’s website reads: “Dan feels honored when he learns that Upright Citizen’s Brigade is performing excerpts from his book, Inside. Blair tries to prove Serena’s suspicions wrong in order to save their friendship. On her way out of town, Ivy ends up on a collision course with the van der Woodsens.”